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. I am already running the game.Spectrophotometric determination of chromium(III) with 2,2'-bipyridyl complex of 3-(5-bromo-2-hydroxy-3-naphthyl)-1,2-propanediol.
A new spectrophotometric method is described for the determination of chromium(III) using the complex of 2,2'-bipyridyl (bpy) with 3-(5-bromo-2-hydroxy-3-naphthyl)-1,2-propanediol (NBA). The method is based on the formation of yellow colored product (complex) at an absorbance maximum of 535 nm when the molar ratio of bpy to Cr(III) is 1 : 2. Beer's law is obeyed up to 3.3 x 10(-5) M of Cr(III) in the range of 1.0 x 10(-6) to 1.0 x 10(-2) M with molar absorptivity of 3.93 x 10(4) l mol(-1) cm(-1). The method is based on the formation of a blue colored complex of Cr(III) with NBA in THF solution and giving well resolved peak at lambda max of 535 nm with molar absorptivity of 1.89 x 10(4) l mol(-1) cm(-1). The method is applied to the determination of chromium(III) in some synthetic mixtures and polluted water samples. In order to confirm the formation of complex, some physicochemical parameters including molar absorptivity, complex constant and molar absorptivity ratio were computed and discussed.                                                                           FILED
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