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NetWrix Disk Space Monitor 4.1.0.27 For Windows
)3(1-3)(H2O)3, C5F5(H2O)4, and C5F5(H2O)4, are used to synthesize poly(arylene ether ketone)s (PARIKs) that are easily soluble in polar and nonpolar organic solvents. The molecular design strategy allows the investigation of the association between the thermochromic property and the hydrophilicity/hydrophobicity of the PAEKs. Fluorescence spectroscopy reveals that the fluorescence intensity of the arylene ethynyl-substituted PAEKs is nearly constant in nonpolar organic solvents, but exhibits increased fluorescence intensity in polar organic solvents. This indicates that there are two types of nano-aggregates in polar organic solvents: small, hydrophobic aggregates with a self-quenching effect and larger, relatively more hydrophilic ones. The thermochromic properties of the PAEKs are highly dependent on the type of substituent in the arylene ring, and significantly affected by the types of substituents. For example, C4F9(H2O)1 shows a high blue-shifted fluorescence emission band and increases in fluorescence intensity upon heating, in both polar and nonpolar organic solvents. C5F5(H2O)3 exhibits a red-shifted fluorescence emission band in polar organic solvents, and decreases in fluorescence intensity upon heating. C5F5(H2O)4 exhibits a blue-shifted fluorescence emission band upon heating in polar organic solvents, as well as an increase in fluorescence intensity. Therefore, these results provide insight into the design of thermochromic polymer materials and practical applications of smart material systems.
## 5.4 Energy-Efficient Agarose Gel-Based Micro/Nanofluidic Devices
Agarose gel is a widely used biocompatible material in many applications including microfluidics [41], DNA separation [42], 3D cell culture [43], soft actuators [44], biosensors [45], and cell encapsulation [46]. Besides its biocompatibility, agarose gel is also an excellent thermo-responsive material with a characteristic melting point between 32 and 49 °C depending on the agarose concentration. Because of these
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