WowTron PDF Page Organizer  Crack+ With Serial Key [Latest] 2022
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Insert new pages to your PDFs and organize them with just a few clicks.Photoinduced copolymerization of propargylic alcohols with maleimides. Part 2: selective formation of cis or trans adducts.
[reaction: see text] The photoinduced copolymerization of propargylic alcohols (CAO, R = H, CH(3), 2-i-Pr, 2-t-Bu, OMe, CN) with maleimides (MA, N=2,4-tBu, N=3,5-Me(2)Si, N=3,5-i-Pr(2), N=3,5-Me(3)Si, N=3,5-Me(2)C(2)H(3)) takes place at ambient temperature. The photoinduced polymerization of [2-t-Bu-4-(1-O-t-Bu-carbobenzyloxy)-3-methoxy-benzyloxy]-propargylic alcohol (1), affording poly(m-t-butyl acrylate) (TBA), can be carried out even in the presence of maleimides with excellent cis-selectivity (1:10, 1:1). This reaction can be explained by a combined "exo-endo" mechanism with the hydrogen-transfer mechanism playing a role in controlling the stereoselectivity. Besides, the photoinduced copolymerization of 1 with N-(1-methoxycarbonyl-2-phenyl-2-(2-pyridyl)ethene maleimide (MCM-1) (1:2) and N-(1,1-dimethylethyl)-2-phenylmaleimide (m-i-Bu-PPM) (1:2) gives the corresponding adducts in moderate to good yields without cis-selectivity. The photoinduced copolymerization of [2-tert-butyl-3-(methoxycarbonyl)-4-(propargyloxy)-4-(propargyloxy)-benzyloxy]-propargylic alcohol (2) with MCM-1 gives the adduct in 45% yield, and the adduct in 73%
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