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Category:Rugby union tours of New Zealand
Category:2018 rugby union tours
Category:2019 in New Zealand rugby union
Category:2018–19 in New Zealand rugby union
Category:2018–19 in European rugby union leaguesUptake of 5-aminolevulinic acid in human glioma and cerebral metastases.
The effect of the intravenous administration of 5-aminolevulinic acid (ALA) on the uptake of its fluorescent metabolite protoporphyrin IX (PpIX) in human brain tumors was investigated using a quantitative autoradiographic procedure. One gram of ALA was administered to 12 patients suffering from brain tumors of various histological origin. The brain tumors selected for this study included a glioblastoma (n = 1), a glioblastoma multiforme (n = 1), a diffuse glioma (n = 1), a meningioma (n = 1), a metastatic melanoma (n = 1), a metastatic carcinoid (n = 1), a metastatic neuroblastoma (n = 1), a medulloblastoma (n = 1), an ependymoblastoma (n = 1), a plexiform neurofibroma (n = 1), and an oligodendroglioma (n = 1). ALA administration resulted in the accumulation of PpIX in the tumor tissue with the highest fluorescence intensity. This accumulation was significantly higher in the tumoral tissue as compared to peritumoral tissue. The highest PpIX levels were measured in the glioblastomas. This is the first study demonstrating the higher accumulation of the fluorescent PpIX derivative in glioblastomas as compared to meningiomas, the tumor type from which ALA is usually administered.Catalytic Functionalization of a Hexahydroindacene-Substituted Dipyrromethane via Visible-Light-Induced [2+2] Photocycloaddition.
In this study, we successfully synthesized the first example of a hexahydroindacene-substituted dipyrromethane via photochemical functionalization. The obtained dipyrromethane, containing hexahydroindacene as the functionalized aromatic ring, has been proved to be highly stable under a variety of experimental conditions and a wide range of functional groups, including acid and base functionalities. 3125841983
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